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Friday, 24 August 2018

Ophthalmic Lenses - 'MR' Resins

If  you are looking for high quality high-indexed premium ophthalmic glasses, the chances are the lens are MR (or Mitsui Resin) lenses, made by Mitsui Chemicals.  MR lenses are used by names like Essilor, Hoya, Nikon, Rodenstock, Seiko and Zeiss - for a comprehensive list, see the end of this article. 




Mitsui Chemicals, Inc. (MCI) 
has over 30 years of experience in the development and production of innovative optical lens materials for the global market. The optical monomer brand name of MR™ is now globally recognized as a premium high index lens material. In 2008, SDC Technologies, Inc., a California based premium coating material company, and in 2011, Acomon group, a leading optical lens material manufacturer well known for its RAV7™ Series of R.I. 1.50 lens material, became MCI group companies. 
Thus MCI is able to provide a full range of lens material and coating solutions to global lens manufacturers.
In 2013, the Korean KOC Solution joined the MCI Group. KOC Solution, a manufacturer and distributor of plastic optical lens monomers, brings with it middle to high-index monomers to greatly enhance MCI's product portfolio.

Mitsui Chemicals, Inc. 
Tokyo, Japan
MCISDCAcomonKOC Solution



R&D Strength
MCI is globally known as a leading manufacturer of urethane products and in 1987 became the first company in the world to apply thiourethane chemical technology to ophthalmic lenses. MCI’s global R&D network with a broad range of technology contributes to excellence in designing the most advanced molecules for ophthalmic lens materials.

For more about MCI R&D Strategy
https://www.mitsuichem.com/en/techno/index.htm
photo_R&D
Sodegaura R&D Center
Chiba, Japan

MR™ Series History
~ Pioneer in high index lens material development ~
Early 1980sStarted development of high index lens materials.
1987Commercial release of MR-6™, the world's first thiourethane high index ophthalmic lens material (R.I.1.60)
1991Commercial release of MR-7™, the world's first refractive index 1.67 ophthalmic lens material
1998Commercial release of MR-10™ (R.I.1.67)
1999Commercial release of MR-8™ (R.I.1.60)
2000Commercial release of MR-174™ (R.I.1.74)
2008Acquisition of SDC Technologies, Inc., a California based premium coating material company
2009Acquisition of Film Specialties, Inc., an anti-fog coating specialty company of SDC Technologies, Inc.
2011Acquisition of Acomon group, a Switzerland and Italy based lens material company
2013Mitsui Chemicals becomes majority shareholder of KOC Solution, a Korea based lens material company

Mitsui Chemicals, Inc. contributes to the development of “epoch making” lens materials to provide the best solution for optical lens users.
Production, Quality Control and CSR
MR™ Series is produced and delivered according to strictly controlled operation protocols for the sustainable supply of high quality materials to lens manufacturers. The MR™ Series production plant is certified under ISO9001 and strict precaution is taken not only in monomer production, but also in packaging, storage and logistics. 
As a chemicals company, human and environmental safety is a top priority. The MR™ Series plant is certified under ISO14001 and all operations are conducted with great consideration to minimize impact on the environment.

For more about MCI CSR
https://www.mitsuichem.com/en/sustainability/index.htm
Photo_CSR
High-end Chemical Plants

Global Network
MR™ Series and RAV7™ Series sales, marketing and technical service are conducted by MCI global headquarters in Japan and 7 regional headquarters around the globe. Therefore, quick customer service in multiple languages is available for the highest customer satisfaction. Additionally, SDC Technologies, Inc. and KOC Solution Co., Ltd. also have global networks to support their customers in each region. Customer satisfaction is always the MCI group’s first priority.
Map_Global Network
https://www.mitsuichem.com/en/special/mr/about/index.htm



MR™ Series Product Lineup

MR™ Series  ~ Trademark of Safe, Clear and Lightweight Lenses ~
Excellent optical materials with high refractive index, high Abbe number, low specific gravity and high impact resistance are provided by polymerizing monomers of MR™ Series. MR™ Series is especially suitable for ophthalmic lenses and is known as the first thiourethane based high index lens material. MR™ Series offers a variety of products to provide the best solution for optical lens users.
Photo_MR_series
 R.I. 1.60: MR-8™
The best balanced high index lens material with the largest share of the R.I. 1.60 lens material market.
MR-8™ is suited to any strength ophthalmic lens and is a new standard in ophthalmic lens material.
 R.I. 1.67: MR-7™ & MR-10™
Global standard R.I.1.67 lens material.
Great materials for thinner lenses with strong impact resistance.
Material Characteristics
MR-7™   : Better color tintability
MR-10™ : Higher heat distortion temperature
 R.I. 1.74: MR-174™
Ultra high index lens material for ultra thin lenses.
Strong prescription lens wearers are now free from thick and heavy lenses.

MR™ Series is a brand name of the raw material for optical lenses.
MR™ Series based lenses are available from most leading lens manufacturers.
>How to produce optical lens using MR™ Series
>Where to buy MR™ Series based lenses

● Comparison of physical properties of lenses made with MR™ Series vs. other optical materials
MR™ SeriesOther
MR-8™MR-7™MR-10™MR-174™Poly
carbonate
Aclyric
(RI:1.60)
Middle
Index
ADC
(CR-39®
RAV7®)
Crown
Glass
Refractive
Index
(ne)
1.601.671.671.741.591.601.551.501.52
Abbe
Number
(νe)
4131313228-303234-365859
Heat
Distortion
Temp. (ºC)
1188510078142-14888-89-84>450
TintabilityGoodExcellentGoodOKNoneGoodGoodGoodNone
Impact
Resistance
GoodGoodGoodOKGoodOKOKOKPoor
Static Load
Resistance
GoodGoodGoodOKGoodPoorPoorGoodGood

* CR-39 is a trademark of PPG Industries, Inc. RAV7 is a trademark of Mitsui Chemicals, Inc. 
All properties are representative measurement figures obtained under specified test methods at Mitsui Chemicals, Inc. and are not guaranteed as specifications.


MR™ Series Features

HIGH REFRACTIVE INDEX for thinner & lighter lenses
  • Optical glasses are now fashionable with light weighted lenses.
  • MR™ Series offers 3 different refractive index products (R.I. 1.60, 1.67, 1.74).
    With higher index materials, it is possible to achieve thinner lenses with the same strength.

SUPERB OPTICAL QUALITY for wearer comfort
  • Both high refractive index and high Abbe number provide optical performance similar to glass lenses.
  • Glass mold-casted MR™ Series shows minimal stress-strain.
    (Optical quality is superior to injection molded polycarbonate lens) 

For more information on Optical Quality
(Abbe Number, Stress Strain)


MR™ Series Features

Optical Quality
Abbe Number
High Abbe number material like MR-8™ minimizes prism effect (Chromatic aberration) of lenses and provides comfortable view to all wearers.
High Abbe Number Material
image Abbe Number
Low Abbe Number Material
image Abbe Number


Strain Free
MR™ Series resin is uniformly polymerized in a glass mold. Compared to the injection molded Polycarbonate lens, MR™ Series lens shows minimal stress strain and offers stress free clear vision.
Stress Strain Observation
(Crossed Nichol method using the polarizing film and white light source)
image Strain Free
MR-8™ offers stress free clear vision




MECHANICAL STRENGTH to protect wearers from accidental injury
  • High impact and static load resistance helps promote wearer eye safety.
    (Pass US-FDA drop ball test standards)
  • Good tensile strength for fashionable rimless frames.
  • Good processability for precisely designed progressive lenses (Advantage of thiourethane materials) .
lens

For more information on Mechanical Strength
(Impact Resistance, Static Load Resistance, Tensile Strength Resistance, Butterfly Test)


Durability during long time use under severe conditions
  • Good weatherability provides minimal change in lens color after years of usage.
  • Good compatibility with coating materials.
For more information on Durability
(Lens Color Change, Coating Compatibility)



PREMIUM LENS APPLICATIONS of the MR™ Series
Wide Color Range Sunglasses
MR™ Series has good color tintability making it suitable for high fashion sunglasses which have special color needs.
TRANSITIONS® Photochromic Lens System
MR™ Series has good compatibility with TRANSITIONS® photochromic lens systems.
Polarized Lens
MR™ Series is widely used for both ophthalmic & plano polarized sunglasses.
Sophisticated Designs
MR™ Series has good mechanical strength and stress free properties making it suitable for various unique lens designs such as "Rimless frame” or “High curve lens".
lens
* TRANSITIONS is a trademark of Transitions Optical, Inc.
All tests were conducted under specified test methods at Mitsui Chemicals, Inc. and are not guaranteed as specifications.

Reference lens samples
CR-39® lens: R.I. 1.50 lens made of CR-39®, Middle index lens: R.I. 1.54-1.56 middle index lens
Polycarbonate lens: R.I.1.59 lens made of polycarbonate, Acrylic lens: R.I.1.60 lens made of acrylic materials

SDC Coating
SDC TECHNOLOGIES

SDC Technologies, Inc.
Irvine, California, USA

SDC Technologies, Inc. is a wholly owned MCI affiliate company and is the recognized world leader in the development and manufacture of abrasion-resistant and functional coatings for application to plastic, glass, and metals. SDC’s products add premium performance, optical clarity, appearance and durability to eyewear, sunglasses, safety lenses, automotive and aeronautical products, electronic devices and other custom applications.

SDC High Index Coating Use on MR™ Series

SDC Technologies Inc. range of high index coating products have been specifically formulated to work with the MR™ Series and provide the best coating and product performance for MR™ Series based lenses.

SDC High Index Coating Features
Index matched
Tintable & Non tintable
Excellent steel wool resistance
AR compatible
Optically clear
Compatible index matched primers

Substrate Applications

SDC Technologies Inc. recognizes that each customer has unique requirements. SDC’s team of Trusted Advisors takes the time to understand customer situations, and then recommends an appropriate solution to meet customer requirements. SDC also works closely with customers during the application process to ensure high quality performance and yields. SDC’s products can be applied in a variety of methods, including dip, spin, flow, spray, and sputter.

Custom Development

Optical
photo_OpticalAs the market leader in premium abrasion-resistant coatings, SDC manufactures a variety of CrystalCoat® coatings and primers for vision corrective lenses and other optical applications. SDC manufactures tintable and non-tintable coatings in both thermal cure and UV cure formulas. CrystalCoat® abrasion-resistant coatings can be applied to all lens substrates. SDC also manufactures high-performance index matched coatings that have been specifically formulated to work with the MR™ Series and provide the best coating and product performance for MR™ Series based lenses.

Sunglasses & Sports Eyewear
photo_Sunglasses & Sports EyewearCrystalCoat® products are recommended for sunglasses and sports eyewear to improve scratch resistance and product durability. CrystalCoat® products can be used on tinted or clear substrates such as MR™ Series, polycarbonate, polyamide, ADC (CR-39®, RAV7®), acrylic and Trivex®. Available globally, SDC products provide tintability, anti-fog, and premium abrasion resistance for sunglass and sports eyewear applications.

Safety
photo_SafetySDC manufactures a broad range of CrystalCoat® products for safety applications. To address the current trend for anti-fog coating, SDC offers high-performance water sheeting, anti-fog coating and abrasion resistance specifically designed to meet the industry's high standards and testing requirements. SDC also offers primer-free coatings with a rapid thermal cure.

Anti-Fog
photo_Automotive & TransitFollowing the recent acquisition of FSI Coating Technologies, Inc. (FSICT), formerly Film Specialties, Inc., SDC now offers a whole new range of premium anti-fog coatings. Solutions that improve product durability include high performance “Water Washable” anti-fog coatings, standard and customized anti-fog coated film and sheet products, as well as complementary hard coating systems and primers. Anti-fog applications include medical, safety, military, and sports eyewear as well as industrial sheet and PET film for commercial freezer display doors.

* CR-39 and Trivex are trademarks of PPG Industries, Inc. RAV7 is a trademark of Mitsui Chemicals, Inc.
https://www.mitsuichem.com/en/special/mr/products/sdc.htm



MR™ Series Lens Production Process

Process

1. Preparation of MR™ Series
illust_Preparation of MR™ Series
Mix MR™ monomer (component) A & B with additives, then degas the MR™ monomer mixture.

2. Filling
Photo_Filling
Fill molds with the MR™ monomer mixture.

3. Polymerization
Photo_Polymerization
Place the filled molds into ovens, where they undergo a heat-cycle, turning the MR™ monomer mixture into a MR™ Series lens.

4. Grinding / Polishing
Photo_Grinding
Grind and polish the surface of the MR™ Series lens to create a curvature for required strength.

5. Tinting
Photo_Tinting
Tint the surface of the MR™ Series lens.

6. Coating
Photo_Coating_1
Hard Coating

Photo_Coating_2
Anti Reflection Coating
Coat the surface of the MR™ Series lens to protect from scratches, reflection etc.

7. Final Inspection
Photo_Final Inspection
Inspect the coated lens.




MR™ Series Manufacturers and Brands (Non-exhaustive list)

Single Vision Lens
CompanyLens Brand
ESSILOR INTERNATIONAL
NIKON ESSILOR CO. LTD.
CARL ZEISS VISION INC.
RODENSTOCK
SEIKO OPTICAL PRODUCTS CO., LTD.
HOYA CORPORATION
ASAHI LITE OPTICAL CO., LTD.
Itoh Optical Industrial Co., Ltd.
TOKAI OPTICAL CO., LTD.
CHEMIGLAS CORPORATION
DAEMYUNG OPTICAL CO., LTD.
SOMO OPTICAL CO., LTD.
KOREA OPTICAL CO., LTD.
HANMI SWISS OPTICAL CO., LTD.
Opticom Co.,Ltd.
Variluxr®
See Max, See Style
Clarlet®
Impression®
SPG, SSU, SLU, ASTERIA, SOLFE, SUPALITE
NULUX, HILUX
HYPER

BELUNA

DAGAS

Clex

Opti SV

Progressive Lens
CompanyLens Brand
ESSILOR INTERNATIONAL
NIKON ESSILOR CO. LTD.
CARL ZEISS VISION INC.


SHAMIR OPTICAL INDUSTRY, LTD.

RODENSTOCK
SEIKO OPTICAL PRODUCTS CO., LTD.
HOYA CORPORATION
ASAHI LITE OPTICAL CO., LTD.
Itoh Optical Industrial Co., Ltd.
TOKAI OPTICAL CO., LTD.
CHEMIGLAS CORPORATION 
DAEMYUNG OPTICAL CO., LTD.
SOMO OPTICAL CO., LTD.
KOREA OPTICAL CO., LTD.
HANMI SWISS OPTICAL CO., LTD.
Opticom Co.,Ltd.
Variluxr®, Anateo® (BBGR)
See Proud, Presio Series
GT2™, Gradal®, AO Compact®, AO Easy,
SOLA Compact ULTRA™, SOLAOne™,
SOLAMAX®
Genesis™, Piccoro®, Attitude™, Creation®
Impression®Free Sign
PAFINA, Perfas, JOYAS
HOYALUX
HYPER VIEW

BELUNA, RESONAS, TOKAI
Chemi-Pro, Chemilux
DAGAS
SOMO LUX
Clex

Opti Profree

Polarized Lens
CompanyLens Brand
ESSILOR INTERNATIONAL
NIKON ESSILOR CO. LTD.
CARL ZEISS VISION INC.
Itoh Optical Industrial Co., Ltd.
SPECIALTY LENS CORPORATION
YOUNGER OPTICS
KBco
Opticom Co.,Ltd.
Essilor® Polarized Lenses
Polashades
SkyPol

iRx Pro™
NuPolar®
Xperio™
PolaMax

MR™ Series lenses are available from many other lens manufacturers around the world.
https://www.mitsuichem.com/en/special/mr/availability/index.htm


Also:  http://ophthalmiclenses.blogspot.com/2012/05/all-about-mr-seriesmr-8-mr-7-mr-10-mr.html



On Lenses, see:

http://ophthalmiclenses.blogspot.com/2012/05/all-about-mr-seriesmr-8-mr-7-mr-10-mr.html

https://healthticket.blogspot.com/2018/08/how-to-choose-best-lenses-for-your.html

https://healthticket.blogspot.com/2020/02/sticker-shock-why-are-glasses-so.html